Modeling with First Order DE’s — Question 3

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Question 3

A specimen contains a stable material of unknown mass BB and an active material of mass R(t)R(t) that disappears from the measured specimen at a rate proportional to RR. Assume the stable material is unaffected and all disappearance products leave the measured mass. Thus the measured mass is M(t)=B+R(t)M(t)=B+R(t). Measurements, treated as exact, are M(0)=100 g,M(1)=70 g,M(2)=55 g,M(0)=100\text{ g},\qquad M(1)=70\text{ g},\qquad M(2)=55\text{ g}, where tt is in days. Assume B≥0B\ge 0, R(0)>0R(0)>0, and a positive constant disappearance coefficient.

Tasks

  1. Formulate the active-mass IVP and the resulting measurement model.

  2. Determine uniquely the stable mass, initial active mass, and disappearance coefficient from the data.

  3. Find the active material’s half-life and the time at which only 55 g of active material remain.

  4. A technician fits exponential decay directly to the total mass using the first two measurements. Test that model against the third measurement and explain the modeling error.

Original worksheet page 1: question and worked solution for 2-7-003
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Question 3 – Solution

Strategy. Separate the unchanging baseline from the decaying component. Differences of equally spaced measurements remove the baseline.

Step 1: Write the component and observation models. The active mass satisfies R′=−kRR'=-kR, where k>0k>0 has units day−1^{-1}. If R(0)=R0R(0)=R_0, then R=R0e−kt,M=B+R0e−kt.R=R_0e^{-kt},\qquad M=B+R_0e^{-kt}. The stable material contributes to the measurement but not to the loss rate.

Step 2: Identify the parameters. Let r=e−kr=e^{-k}, where one day is the time step, so 0<r<10<r<1. The measured successive differences satisfy −30=R0(r−1),−15=R0r(r−1).-30=R_0(r-1),\qquad -15=R_0r(r-1). Their ratio gives r=1/2r=1/2. Therefore R0=60 g,B=40 g,k=ln⁡2 day−1,M(t)=40+602−t.\boxed{R_0=60\text{ g},\quad B=40\text{ g},\quad k=\ln 2\text{ day}^{-1}},\qquad \boxed{M(t)=40+60\,2^{-t}}. These values reproduce 100,70,55100,70,55 g. They are unique under the assumptions because the nonzero first difference fixes rr, then R0R_0, then BB. Also R′=−kRR'=-kR verifies the rate law.

Step 3: Compute active-mass times. The active half-life is ln⁡2/k=1 day\ln 2/k=\boxed{1\text{ day}}. The condition R=5R=5 gives 602−t=560\,2^{-t}=5, hence t=ln⁡12ln⁡2≈3.585 days.\boxed{t=\frac{\ln 12}{\ln 2}\approx 3.585\text{ days}}. The active mass is below 55 g after that time. The total mass then is 4545 g, not 55 g.

Step 4: Test the incorrect observation model. A single exponential through the first two total-mass measurements is M̃(t)=100(0.7)t\widetilde M(t)=100(0.7)^t. It predicts M̃(2)=49\widetilde M(2)=49 g, contradicting the measured 5555 g. It wrongly assigns the stable component the same disappearance law as the active material and predicts a zero limiting total mass instead of 4040 g.

The model is intended for t≥0t\ge 0. Its inference depends on exact data, constant kk, and a truly constant baseline; noisy data would require an estimation method rather than exact identification from three values.

Original worksheet page 2: question and worked solution for 2-7-003

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